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doi: 10.1158/0008-5472.CAN-07-0783

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The degree of dissociation α for acids is defined as: Combining Equations 1 and 2 leads to (for anions): However, for concentrated solutions or pK a ’s near the extremes of the pH scale, it has been shown that there are significant differences between the predicted and actual concentration of the hydrogen ion.8 Since the Henderson-Hasselbalch equation only gives accurate results for dilute acids in aqueous solutions, another formula for the quantification of acid strength was developed by Hammett.9 Instead of measuring the concentration of the species present in solution, Hammett described the strength of an acid as the relation between the hydrogen ion activity (a) and the activity coefficients (f) of the various species in solution

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